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Issue 62, 2012

Water compatibility and organic transformations of organo-Zintl deltahedral clusters

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Abstract

We report the remarkable stability of di-substituted organo-Zintl deltahedral clusters in the presence of water. This has been exploited in a reaction at the organic substituents of the cluster which produces water as a by-product. Also reported are the synthesis, characterization, and crystal structure of [K-krypt]2[Ge9–(CH[double bond, length as m-dash]CH–CH2NH2)2] involved in the reaction.

Graphical abstract: Water compatibility and organic transformations of organo-Zintl deltahedral clusters

Supplementary files

Article information


Submitted
28 Mar 2012
Accepted
26 Apr 2012
First published
27 Apr 2012

Chem. Commun., 2012,48, 7720-7722
Article type
Communication

Water compatibility and organic transformations of organo-Zintl deltahedral clusters

M. W. Hull and S. C. Sevov, Chem. Commun., 2012, 48, 7720 DOI: 10.1039/C2CC32263C

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