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Issue 67, 2012
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Evidence for magnetic anisotropy of [NbIV(CN)8]4− in a pillared-layered Mn2Nb framework showing spin-flop transition

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Abstract

The first example of the [Nb(CN)8]-based pillared-layered-type framework system {[MnII2(bpdo)(H2O)4][NbIV(CN)8]·6H2O}n (bpdo = 4,4′-bipyridyl-N,N′-dioxide) has been obtained and characterized structurally and magnetically. The presented results provide the first evidence for substantial magnetic anisotropy of [NbIV(CN)8].

Graphical abstract: Evidence for magnetic anisotropy of [NbIV(CN)8]4− in a pillared-layered Mn2Nb framework showing spin-flop transition

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Article information


Submitted
27 Mar 2012
Accepted
17 Apr 2012
First published
18 Apr 2012

Chem. Commun., 2012,48, 8323-8325
Article type
Communication

Evidence for magnetic anisotropy of [NbIV(CN)8]4− in a pillared-layered Mn2Nb framework showing spin-flop transition

D. Pinkowicz, M. Rams, W. Nitek, B. Czarnecki and B. Sieklucka, Chem. Commun., 2012, 48, 8323
DOI: 10.1039/C2CC32234J

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