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Issue 54, 2012
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A non-fused mono-meso-free pentaphyrin and its rhodium(i) complex

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Abstract

5,10,15,20-Tetrakis(pentafluorophenyl) [22]pentaphyrin(1.1.1.1.1) 7 was synthesised and its bis-rhodium(I) complex 12 has been revealed to be a non-fused, yet planar pentaphyrin with an inverted pyrrole. Both 7 and 12 are aromatic, showing sharp Soret-like bands and diatropic ring currents.

Graphical abstract: A non-fused mono-meso-free pentaphyrin and its rhodium(i) complex

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Publication details

The article was received on 21 Mar 2012, accepted on 10 May 2012 and first published on 18 May 2012


Article type: Communication
DOI: 10.1039/C2CC32054A
Chem. Commun., 2012,48, 6785-6787

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    A non-fused mono-meso-free pentaphyrin and its rhodium(I) complex

    T. Yoneda, H. Mori, B. Sun Lee, M. Yoon, D. Kim and A. Osuka, Chem. Commun., 2012, 48, 6785
    DOI: 10.1039/C2CC32054A

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