Jump to main content
Jump to site search
PLANNED MAINTENANCE Close the message box

Scheduled maintenance work on Wednesday 22nd May 2019 from 11:00 AM to 1:00 PM (GMT).

During this time our website performance may be temporarily affected. We apologise for any inconvenience this might cause and thank you for your patience.


Issue 50, 2012
Previous Article Next Article

Copper-induced N–N bond cleavage results in an octanuclear expanded-core grid-like complex

Author affiliations

Abstract

Reaction of copper(I) acetate and 4-amino-3,5-di(2-pyridyl)-1,2,4-triazole (adpt) in methanol under ambient conditions yields octanuclear [CuII8(dpt)4(OH)4(OAc)8]; OAc = acetate anion, and dpt = anion of deaminated adpt, 3,5-di(2-pyridyl)-1,2,4-triazolate. However, reaction of copper(II) acetate with dptH gives tetranuclear [CuII4(dpt)2(OH)(OMe)(OAc)4].

Graphical abstract: Copper-induced N–N bond cleavage results in an octanuclear expanded-core grid-like complex

Back to tab navigation

Supplementary files

Publication details

The article was received on 19 Mar 2012, accepted on 21 Apr 2012 and first published on 24 Apr 2012


Article type: Communication
DOI: 10.1039/C2CC32018E
Chem. Commun., 2012,48, 6229-6231

  •   Request permissions

    Copper-induced N–N bond cleavage results in an octanuclear expanded-core grid-like complex

    N. G. White, J. A. Kitchen, J. A. Joule and S. Brooker, Chem. Commun., 2012, 48, 6229
    DOI: 10.1039/C2CC32018E

Search articles by author

Spotlight

Advertisements