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Issue 45, 2012
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Design of chiral sulfoxide–Schiff base hybrids and their application in Cu-catalyzed asymmetric Henry reactions

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Abstract

A new class of chiral sulfoxide–Schiff base ligands has been developed by the rational combination of two privileged chiral backbones. These sulfoxide–Schiff base ligands were found to be highly efficient for Cu-catalyzed asymmetric Henry reactions (up to 98% yield and 96% ee).

Graphical abstract: Design of chiral sulfoxide–Schiff base hybrids and their application in Cu-catalyzed asymmetric Henry reactions

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Publication details

The article was received on 15 Mar 2012, accepted on 16 Apr 2012 and first published on 17 Apr 2012


Article type: Communication
DOI: 10.1039/C2CC31907A
Chem. Commun., 2012,48, 5596-5598

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    Design of chiral sulfoxide–Schiff base hybrids and their application in Cu-catalyzed asymmetric Henry reactions

    H. Cheng, L. Lu, T. Wang, J. Chen and W. Xiao, Chem. Commun., 2012, 48, 5596
    DOI: 10.1039/C2CC31907A

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