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Issue 45, 2012
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Design of chiral sulfoxide–Schiff base hybrids and their application in Cu-catalyzed asymmetric Henry reactions

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Abstract

A new class of chiral sulfoxide–Schiff base ligands has been developed by the rational combination of two privileged chiral backbones. These sulfoxide–Schiff base ligands were found to be highly efficient for Cu-catalyzed asymmetric Henry reactions (up to 98% yield and 96% ee).

Graphical abstract: Design of chiral sulfoxide–Schiff base hybrids and their application in Cu-catalyzed asymmetric Henry reactions

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Article information


Submitted
15 Mar 2012
Accepted
16 Apr 2012
First published
17 Apr 2012

Chem. Commun., 2012,48, 5596-5598
Article type
Communication

Design of chiral sulfoxide–Schiff base hybrids and their application in Cu-catalyzed asymmetric Henry reactions

H. Cheng, L. Lu, T. Wang, J. Chen and W. Xiao, Chem. Commun., 2012, 48, 5596
DOI: 10.1039/C2CC31907A

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