Issue 45, 2012
From the journal:

Chemical Communications

Design of chiral sulfoxide–Schiff base hybrids and their application in Cu-catalyzed asymmetric Henry reactions†

Hong-Gang Cheng,a   Liang-Qiu Lu,a   Tao Wang,a   Jia-Rong Chen*a  and  Wen-Jing Xiao*a  

* Corresponding authors

a Key Laboratory of Pesticide & Chemical Biology, Ministry of Education, College of Chemistry, Central China Normal University, 152 Luoyu Road, Wuhan, China
E-mail: jiarongchen2003@yahoo.com.cn, wxiao@mail.ccnu.edu.cn
Fax: +86 27 67862041
Tel: +86 27 67862041

Abstract

A new class of chiral sulfoxide–Schiff base ligands has been developed by the rational combination of two privileged chiral backbones. These sulfoxide–Schiff base ligands were found to be highly efficient for Cu-catalyzed asymmetric Henry reactions (up to 98% yield and 96% ee).

Graphical abstract: Design of chiral sulfoxide–Schiff base hybrids and their application in Cu-catalyzed asymmetric Henry reactions

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Article information

DOI
https://doi.org/10.1039/C2CC31907A
Article type
Communication
Submitted
15 Mar 2012
Accepted
16 Apr 2012
First published
17 Apr 2012

Chem. Commun., 2012,48, 5596-5598

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Design of chiral sulfoxide–Schiff base hybrids and their application in Cu-catalyzed asymmetric Henry reactions

H. Cheng, L. Lu, T. Wang, J. Chen and W. Xiao, Chem. Commun., 2012, 48, 5596 DOI: 10.1039/C2CC31907A

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