Issue 47, 2012
From the journal:

Chemical Communications

Ruthenium(iv) porphyrin catalyzed phosphoramidation of aldehydes with phosphoryl azides as a nitrene source†‡

Wenbo Xiao,a   Cong-Ying Zhoua  and  Chi-Ming Che*a  

* Corresponding authors

a Department of Chemistry, State Key Laboratory of Synthetic Chemistry, and Open Laboratory of Chemical Biology of the Institute of Molecular Technology for Drug Discovery and Synthesis, The University of Hong Kong, Pokfulam Road, Hong Kong, China
E-mail: cmche@hku.hk
Fax: +852 2857-1586
Tel: +852 2859-2154

Abstract

[RuIV(por)Cl2] (por = porphyrin dianion) can efficiently catalyze nitrene insertion into aldehyde C–H bonds with phosphoryl azides as a nitrene source to give N-acylphosphoramidates in good to high yields.

Graphical abstract: Ruthenium(iv) porphyrin catalyzed phosphoramidation of aldehydes with phosphoryl azides as a nitrene source

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Article information

DOI
https://doi.org/10.1039/C2CC31686B
Article type
Communication
Submitted
07 Mar 2012
Accepted
20 Apr 2012
First published
09 May 2012

Chem. Commun., 2012,48, 5871-5873

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Ruthenium(IV) porphyrin catalyzed phosphoramidation of aldehydes with phosphoryl azides as a nitrene source

W. Xiao, C. Zhou and C. Che, Chem. Commun., 2012, 48, 5871 DOI: 10.1039/C2CC31686B

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