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Issue 44, 2012

Trichlorosilyl triflate-mediated enantioselective directed cross-aldol reaction between ketones using a chiral phosphine oxide as an organocatalyst

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Abstract

Trichlorosilyl triflate-promoted directed cross-aldol reaction between ketones in the presence of a chiral phosphine oxide as an organocatalyst is described. This is the first enantioselective cross-aldol reaction between simple ketones with good enantioselectivity.

Graphical abstract: Trichlorosilyl triflate-mediated enantioselective directed cross-aldol reaction between ketones using a chiral phosphine oxide as an organocatalyst

Supplementary files

Article information


Submitted
29 Feb 2012
Accepted
10 Apr 2012
First published
27 Apr 2012

Chem. Commun., 2012,48, 5524-5526
Article type
Communication

Trichlorosilyl triflate-mediated enantioselective directed cross-aldol reaction between ketones using a chiral phosphine oxide as an organocatalyst

S. Aoki, S. Kotani, M. Sugiura and M. Nakajima, Chem. Commun., 2012, 48, 5524 DOI: 10.1039/C2CC31543B

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