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Issue 52, 2012
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Targeted functionalisation of a hierarchically-structured porous coordination polymer crystal enhances its entire function

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Abstract

Spatiospecific functionalisation of a shell crystal was performed in a core–shell crystal of a porous coordination polymer (PCP) via post-synthetic modification (PSM). The shell crystal allowed the core crystal to selectively accumulate N,N-dimethylaniline (DMA) and afford the intense exciplex fluorescence.

Graphical abstract: Targeted functionalisation of a hierarchically-structured porous coordination polymer crystal enhances its entire function

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Article information


Submitted
26 Feb 2012
Accepted
30 Mar 2012
First published
02 Apr 2012

Chem. Commun., 2012,48, 6472-6474
Article type
Communication

Targeted functionalisation of a hierarchically-structured porous coordination polymer crystal enhances its entire function

K. Hirai, S. Furukawa, M. Kondo, M. Meilikhov, Y. Sakata, O. Sakata and S. Kitagawa, Chem. Commun., 2012, 48, 6472
DOI: 10.1039/C2CC31421E

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