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Issue 52, 2012
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NTCDA–TTF first axial fusion: emergent panchromatic, NIR optical, multi-state redox and high optical contrast photooxidation

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Abstract

The first synthetic entry into axially fused NTCDA/PMDA–TTF multipolar molecules demonstrates a high optical contrast photooxidation, panchromism, low HOMO–LUMO gap, generation of a stable radical cation, NIR absorption/emission beyond 2150/800 nm and theoretically calculated NLO activity.

Graphical abstract: NTCDA–TTF first axial fusion: emergent panchromatic, NIR optical, multi-state redox and high optical contrast photooxidation

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Publication details

The article was received on 20 Feb 2012, accepted on 08 Apr 2012 and first published on 10 Apr 2012


Article type: Communication
DOI: 10.1039/C2CC31274C
Citation: Chem. Commun., 2012,48, 6475-6477
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    NTCDA–TTF first axial fusion: emergent panchromatic, NIR optical, multi-state redox and high optical contrast photooxidation

    D. Asthana, M. R. Ajayakumar, R. P. Pant and P. Mukhopadhyay, Chem. Commun., 2012, 48, 6475
    DOI: 10.1039/C2CC31274C

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