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Issue 38, 2012
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A début for base stabilized monoalkylsilylenes

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Abstract

The first base stabilized monoalkylsilylenes LSitBu (2) and LSi[C(SiMe3)3] (3) (L = PhC(NtBu)2) were synthesized by the facile metathesis reactions of LitBu and KC(SiMe3)3 with LSiCl (1). The reaction of LSitBu (2) with N2O afforded the dimer [LSitBu(μ-O)]2 (4) which contains a four-membered Si2O2 ring.

Graphical abstract: A début for base stabilized monoalkylsilylenes

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Supplementary files

Article information


Submitted
13 Feb 2012
Accepted
14 Mar 2012
First published
15 Mar 2012

Chem. Commun., 2012,48, 4561-4563
Article type
Communication

A début for base stabilized monoalkylsilylenes

R. Azhakar, R. S. Ghadwal, H. W. Roesky, H. Wolf and D. Stalke, Chem. Commun., 2012, 48, 4561 DOI: 10.1039/C2CC31041D

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