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Issue 44, 2012
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Hydrogenation effects in metalloporphycenes: synthesis and redox behavior of Ni(II)–tetra(n-propyl)dihydroporphycene

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Abstract

Hydrogenated tetrapropylporphycenes, 2,3-dihydro-2,7,12,17-tetrapropylporphycene 1 and its NiII complex 2, have been prepared and the hydrogenation effects on their electronic structure characterized. A one-electron reduction of 2 promotes dehalogenation of organic halides whose observation is unprecedented for the porphycene compounds.

Graphical abstract: Hydrogenation effects in metalloporphycenes: synthesis and redox behavior of Ni(ii)–tetra(n-propyl)dihydroporphycene

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Publication details

The article was received on 10 Feb 2012, accepted on 27 Mar 2012 and first published on 28 Mar 2012


Article type: Communication
DOI: 10.1039/C2CC30991B
Citation: Chem. Commun., 2012,48, 5413-5415

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    Hydrogenation effects in metalloporphycenes: synthesis and redox behavior of Ni(II)–tetra(n-propyl)dihydroporphycene

    T. Okawara, K. Hashimoto, M. Abe, H. Shimakoshi and Y. Hisaeda, Chem. Commun., 2012, 48, 5413
    DOI: 10.1039/C2CC30991B

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