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Issue 40, 2012
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Calix[4]arene-based metal–organic frameworks: towards hierarchically porous materials

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Abstract

An upper rim-functionalised calix[4]arene dicarboxylic acid (H2caldc) has been used to prepare four metal–organic frameworks, three of which have been structurally characterised and shown to form two- or three-dimensional network structures. Simulations suggest that such networks are likely to display interesting selectivity to guest molecules.

Graphical abstract: Calix[4]arene-based metal–organic frameworks: towards hierarchically porous materials

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Article information


Submitted
10 Feb 2012
Accepted
21 Mar 2012
First published
22 Mar 2012

Chem. Commun., 2012,48, 4824-4826
Article type
Communication

Calix[4]arene-based metal–organic frameworks: towards hierarchically porous materials

S. P. Bew, A. D. Burrows, T. Düren, M. F. Mahon, P. Z. Moghadam, V. M. Sebestyen and S. Thurston, Chem. Commun., 2012, 48, 4824
DOI: 10.1039/C2CC30988B

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