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Issue 36, 2012
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Post-synthetic modification of isomorphic coordination layers: exchange dynamics of metal ions in a single crystal to single crystal fashion

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Abstract

A diverse set of guest molecules template the consistent formation of fifteen iso-structural layered structures containing a pyridine based tripodal ligand, divalent metal ions and anions. These materials have shown a remarkable ability to interconvert from Zn(II) to Cu(II), Cd(II) to Cu(II), Cu(II) to Cd(II) complexes in a SCSC (single crystal-to-single crystal) fashion.

Graphical abstract: Post-synthetic modification of isomorphic coordination layers: exchange dynamics of metal ions in a single crystal to single crystal fashion

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Article information


Submitted
10 Feb 2012
Accepted
06 Mar 2012
First published
08 Mar 2012

Chem. Commun., 2012,48, 4293-4295
Article type
Communication

Post-synthetic modification of isomorphic coordination layers: exchange dynamics of metal ions in a single crystal to single crystal fashion

G. Mukherjee and K. Biradha, Chem. Commun., 2012, 48, 4293
DOI: 10.1039/C2CC30983A

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