Issue 62, 2012
From the journal:

Chemical Communications

Chiroptical properties of an alternatingly functionalized cellotriose bearing two porphyrin groups†

Keita Sakakibara,*ab   Fumiaki Nakatsubo,c   Alfred D. Frenchd  and  Thomas Rosenau*a  

* Corresponding authors

a Department of Chemistry, University of Natural Resources and Life Sciences (BOKU), Muthgasse 18, Vienna A-1190, Austria
E-mail: thomas.rosenau@boku.ac.at
Fax: +43-1-47654 6059
Tel: +43-1-47654 6071

b Institute for Chemical Research, Kyoto University, Gokasho, Uji, Japan
E-mail: sakakibara.keita.4n@kyoto-u.ac.jp
Fax: +81-774-38-3170
Tel: +81-774-38-3168

c Research Institute for Sustainable Humanosphere, Kyoto University, Gokasho, Uji, Japan

d Southern Regional Research Center, U. S. Department of Agriculture, 1100 Robert E. Lee Blvd, New Orleans, USA

Abstract

Right-handedness derived from bisporphyrins attached to a cellotriose backbone at O-6 and O′′-6 positions is revealed for the first time. This cellotriose is proposed as a model of alternatingly functionalized cellulosics, which have promising properties for applications in optoelectronics and molecular receptors owing to the chirality and rigid backbone effects.

Graphical abstract: Chiroptical properties of an alternatingly functionalized cellotriose bearing two porphyrin groups

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Article information

DOI
https://doi.org/10.1039/C2CC30805C
Article type
Communication
Submitted
04 Feb 2012
Accepted
21 Mar 2012
First published
22 Mar 2012

Chem. Commun., 2012,48, 7672-7674

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Chiroptical properties of an alternatingly functionalized cellotriose bearing two porphyrin groups

K. Sakakibara, F. Nakatsubo, A. D. French and T. Rosenau, Chem. Commun., 2012, 48, 7672 DOI: 10.1039/C2CC30805C

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