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Issue 38, 2012
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Magnesium-catalysed hydroboration of aldehydes and ketones

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Abstract

The heteroleptic magnesium alkyl complex [CH{C(Me)NAr}2MgnBu] (Ar = 2,6-iPr2C6H3) is reported as a highly efficient pre-catalyst for the hydroboration of aldehydes and ketones with pinacolborane.

Graphical abstract: Magnesium-catalysed hydroboration of aldehydes and ketones

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Article information


Submitted
25 Jan 2012
Accepted
07 Mar 2012
First published
08 Mar 2012

Chem. Commun., 2012,48, 4567-4569
Article type
Communication

Magnesium-catalysed hydroboration of aldehydes and ketones

M. Arrowsmith, T. J. Hadlington, M. S. Hill and G. Kociok-Köhn, Chem. Commun., 2012, 48, 4567 DOI: 10.1039/C2CC30565H

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