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Issue 31, 2012
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Helicity inversion from left- to right-handed square planar Pd(II) complexes: synthesis of a diastereomer pair from a single chiral ligand and their structure dynamism

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Abstract

A diastereomer pair of left- and right-handed square planar Pd(II) complexes was synthesized from a single chiral ligand as kinetic and thermodynamic products. Helicity inversion between the diastereomers occurred rapidly under thermal and microwave irradiation conditions.

Graphical abstract: Helicity inversion from left- to right-handed square planar Pd(ii) complexes: synthesis of a diastereomer pair from a single chiral ligand and their structure dynamism

  • This article is part of the themed collection: Chirality
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Publication details

The article was received on 30 Dec 2011, accepted on 21 Feb 2012 and first published on 08 Mar 2012


Article type: Communication
DOI: 10.1039/C2CC18154A
Citation: Chem. Commun., 2012,48, 3721-3723
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    Helicity inversion from left- to right-handed square planar Pd(II) complexes: synthesis of a diastereomer pair from a single chiral ligand and their structure dynamism

    H. Miyake, M. Ueda, S. Murota, H. Sugimoto and H. Tsukube, Chem. Commun., 2012, 48, 3721
    DOI: 10.1039/C2CC18154A

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