Issue 30, 2012
From the journal:

Chemical Communications

Phosphaalkenyl germylenes and their gold, tungsten and molybdenum complexes†

Dimitri Matioszek,ab   Tibor-Gabor Kocsor,abc   Annie Castel,*ab   Gabriela Nemes,*c   Jean Escudiéab  and  Nathalie Saffond  

* Corresponding authors

a Université de Toulouse, UPS, LHFA, 118 Route de Narbonne, F-31062 Toulouse, France
E-mail: castel@chimie.ups-tlse.fr

b CNRS, LHFA, UMR 5069, F-31062 Toulouse Cedex 9, France

c Universitatea Babeş-Bolyai, Facultatea de Chimie şi Inginerie Chimică, str. Kogalniceanu, nr; 1, Cluj-Napoca, Romania
E-mail: sgabi@chem.ubbcluj.ro

d Service Commun Rayons X, Institut de Chimie de Toulouse, ICT- FR2599, Université Paul Sabatier, UPS, 118 Route de Narbonne, F-31062 Toulouse Cedex 9, France

Abstract

The new bis(phosphaalkenyl) germanium(II) compound (NHC)Ge(CCl[double bond, length as m-dash]PMes*)2 reacts with L2M(CO)4 (M = Mo, W) to give bidentate complexes with an unexpected coordinating behaviour involving the Ge(II) centre and one phosphorus atom, and with AuI or Me2SAuCl to afford the monodentate complexes coordinated at the germanium(II) atom.

Graphical abstract: Phosphaalkenyl germylenes and their gold, tungsten and molybdenum complexes

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Article information

DOI
https://doi.org/10.1039/C2CC17551G
Article type
Communication
Submitted
02 Dec 2011
Accepted
17 Feb 2012
First published
20 Feb 2012

Chem. Commun., 2012,48, 3629-3631

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Phosphaalkenyl germylenes and their gold, tungsten and molybdenum complexes

D. Matioszek, T. Kocsor, A. Castel, G. Nemes, J. Escudié and N. Saffon, Chem. Commun., 2012, 48, 3629 DOI: 10.1039/C2CC17551G

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