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Issue 21, 2012
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High yield synthesis of a neutral and carbonyl-rich terminal arylborylene complex

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Abstract

High yield synthesis of trans-[(Me3P)(OC)3Fe = BDur] (Dur, “Duryl” = 2,3,4,6-Me4C6H) is achieved by salt elimination and subsequent liberation of trimethylsilylbromide from K[Fe(CO)3(PMe3)SiMe3] and Br2BDur.

Graphical abstract: High yield synthesis of a neutral and carbonyl-rich terminal arylborylene complex

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Publication details

The article was received on 29 Nov 2011, accepted on 23 Jan 2012 and first published on 23 Jan 2012


Article type: Communication
DOI: 10.1039/C2CC17445F
Citation: Chem. Commun., 2012,48, 2701-2703
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    High yield synthesis of a neutral and carbonyl-rich terminal arylborylene complex

    H. Braunschweig, Q. Ye and K. Radacki, Chem. Commun., 2012, 48, 2701
    DOI: 10.1039/C2CC17445F

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