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Abstract | Cited by

An (alkene)peroxoiridium(III) complex, [Ir(L)(cod)(O2)] [where LH = PhN[double bond, length as m-dash]C(NMe2)NHPh and cod = 1,5-cyclooctadiene], was identified as an intermediate in the reaction of the IrI precursor [Ir(L)(cod)] with O2 and characterized by spectroscopic methods. Decay of the intermediate and further reaction with 1,5-cyclooctadiene produced 4-cycloocten-1-one.

Graphical abstract: Evidence for a reactive (alkene)peroxoiridium(iii) intermediate in the oxidation of an alkene complex with O2

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