Issue 32, 2012
From the journal:

Chemical Communications

A stereoselectively deuterated supramolecular motif to probe the role of solvent during self-assembly processes†‡

Seda Cantekin,a   Yoko Nakano,a   Jeffrey C. Everts,ab   Paul van der Schoot,*bc   E. W. Meijer*a  and  Anja R. A. Palmans*a  

* Corresponding authors

a Institute for Complex Molecular Systems, Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven, The Netherlands
E-mail: e.w.meijer@tue.nl, a.palmans@tue.nl
Fax: +31 (0)40 2451036
Tel: +31 (0)40 2473101

b Group Theory of Polymers and Soft Matter, Department of Applied Physics, Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven, The Netherlands
E-mail: p.v.d.schoot@tue.nl

c Instituut voor Theoretische Fysica, Universiteit Utrecht, Leuvenlaan 4, 3584 CE Utrecht, The Netherlands

Abstract

Small changes in the alkane solvent structure in combination with temperature effects lead to four different conformations of stereoselectively deuterated benzene-1,3,5-tricarboxamides in the aggregated state, affecting the expression of the supramolecular chirality and highlighting the role of the solvent structure in self-assembly processes.

Graphical abstract: A stereoselectively deuterated supramolecular motif to probe the role of solvent during self-assembly processes

  • This article is part of the themed collection: Chirality
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Article information

DOI
https://doi.org/10.1039/C2CC17284D
Article type
Communication
Submitted
22 Nov 2011
Accepted
05 Jan 2012
First published
25 Jan 2012

Chem. Commun., 2012,48, 3803-3805

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A stereoselectively deuterated supramolecular motif to probe the role of solvent during self-assembly processes

S. Cantekin, Y. Nakano, J. C. Everts, P. van der Schoot, E. W. Meijer and A. R. A. Palmans, Chem. Commun., 2012, 48, 3803 DOI: 10.1039/C2CC17284D

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