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Abstract | Cited by

The thermal or photochemical reactions of Cp*IrS2C2B10H10 (1) and aryl azides lead to C–C coupling via C(sp3)–H activation in 2 as well as the formation of C–S bonds and new-type SSN pincer ligands in 3–8 through ortho-substituted electron-withdrawing group migration over an aryl ring.

Graphical abstract: Unusual group migration and C(sp3)–H activation leading to stable metallacycles in the reactions of Cp*IrS2C2B10H10 and aryl azides

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