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Issue 16, 2012

Asymmetric oxidative Lewis base catalysis—unifying iminium and enamine organocatalysis with oxidations

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Abstract

Enantioselective oxidative domino reactions of allylic alcohols to functionalized aldehydes have been developed. The one pot domino oxidation-iminium activation represents a convenient strategy for the enantioselective addition of malonates to allylic alcohols and the asymmetric formation of formyl cyclopropanes.

Graphical abstract: Asymmetric oxidative Lewis base catalysis—unifying iminium and enamine organocatalysis with oxidations

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Article information


Submitted
17 Oct 2011
Accepted
01 Dec 2011
First published
17 Jan 2012

Chem. Commun., 2012,48, 2201-2203
Article type
Communication

Asymmetric oxidative Lewis base catalysis—unifying iminium and enamine organocatalysis with oxidations

M. Rueping, H. Sundén, L. Hubener and E. Sugiono, Chem. Commun., 2012, 48, 2201 DOI: 10.1039/C2CC16447G

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