A novel high-spin tridecanuclear NiII cluster with an azido-bridged core exhibiting disk-like topology

Gabriel Brunet; Fatemah Habib; Cyril Cook; Thushan Pathmalingam; Francis Loiseau; Ilia Korobkov; Tara J. Burchell; André M. Beauchemin; Muralee Murugesu

doi:10.1039/C2CC16221K

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

A novel high-spin tridecanuclear Ni^II cluster with an azido-bridged core exhibiting disk-like topology†

Gabriel Brunet,^a Fatemah Habib,^a Cyril Cook,^a Thushan Pathmalingam,^a Francis Loiseau,^a Ilia Korobkov,^a Tara J. Burchell,^a André M. Beauchemin^ab and Muralee Murugesu*^ab

Author affiliations

* Corresponding authors

^a Department of Chemistry, University of Ottawa, 10 Marie-Curie, Ottawa, ON, Canada
E-mail: m.murugesu@uottawa.ca
Fax: +1 613 562 5170
Tel: +1 613 562 5800-2733

^b Centre for Catalysis Research and Innovation, 30 Marie-Curie, Ottawa, ON, Canada

Abstract

A high-spin tridecanuclear Ni^II cluster, [Ni^II₁₃(N₃)₁₈(dpo)₄(Hdpo)₂(H₂hpo)₄(H₂O)(MeOH)] [Ni^II₁₃(N₃)₁₈(dpo)₄(Hdpo)₂(H₂hpo)₄(H₂O)₂] (1) (Hdpo = 1-(dimethylamino)propan-2-one oxime and H₂hpo = 1-(hydroxyamino)propan-2-one oxime) with a purely azido-bridged core, is reported with dominant ferromagnetic coupling between Ni^II ions. The latter molecule exhibits a unique planar core topology with the largest N₃⁻ : Ni^II ratio reported to date.

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/C2CC16221K
Article type: Communication
Submitted: 06 Oct 2011
Accepted: 29 Nov 2011
First published: 29 Nov 2011

Download Citation

Chem. Commun., 2012,48, 1287-1289

Permissions

Request permissions

A novel high-spin tridecanuclear Ni^II cluster with an azido-bridged core exhibiting disk-like topology

G. Brunet, F. Habib, C. Cook, T. Pathmalingam, F. Loiseau, I. Korobkov, T. J. Burchell, A. M. Beauchemin and M. Murugesu, Chem. Commun., 2012, 48, 1287 DOI: 10.1039/C2CC16221K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications