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Issue 9, 2012
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A novel high-spin tridecanuclear NiII cluster with an azido-bridged core exhibiting disk-like topology

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Abstract

A high-spin tridecanuclear NiII cluster, [NiII13(N3)18(dpo)4(Hdpo)2(H2hpo)4(H2O)(MeOH)] [NiII13(N3)18(dpo)4(Hdpo)2(H2hpo)4(H2O)2] (1) (Hdpo = 1-(dimethylamino)propan-2-one oxime and H2hpo = 1-(hydroxyamino)propan-2-one oxime) with a purely azido-bridged core, is reported with dominant ferromagnetic coupling between NiII ions. The latter molecule exhibits a unique planar core topology with the largest N3 : NiII ratio reported to date.

Graphical abstract: A novel high-spin tridecanuclear NiII cluster with an azido-bridged core exhibiting disk-like topology

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Publication details

The article was received on 06 Oct 2011, accepted on 29 Nov 2011 and first published on 29 Nov 2011


Article type: Communication
DOI: 10.1039/C2CC16221K
Citation: Chem. Commun., 2012,48, 1287-1289
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    A novel high-spin tridecanuclear NiII cluster with an azido-bridged core exhibiting disk-like topology

    G. Brunet, F. Habib, C. Cook, T. Pathmalingam, F. Loiseau, I. Korobkov, T. J. Burchell, A. M. Beauchemin and M. Murugesu, Chem. Commun., 2012, 48, 1287
    DOI: 10.1039/C2CC16221K

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