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Issue 9, 2012
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Suzuki–Miyaura cross-couplings of secondary allylic boronic esters

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Abstract

Palladium-catalyzed cross-coupling reactions of secondary allylic boronic esters with iodoarenes were demonstrated under the conditions previously described for the coupling of benzylic substrates. The regioselectivity of the process was largely dictated by the pattern of olefin substitution.

Graphical abstract: Suzuki–Miyaura cross-couplings of secondary allylic boronic esters

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Publication details

The article was received on 29 Sep 2011, accepted on 25 Nov 2011 and first published on 19 Dec 2011


Article type: Communication
DOI: 10.1039/C2CC16076E
Chem. Commun., 2012,48, 1230-1232

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    Suzuki–Miyaura cross-couplings of secondary allylic boronic esters

    B. W. Glasspoole, K. Ghozati, J. W. Moir and C. M. Crudden, Chem. Commun., 2012, 48, 1230
    DOI: 10.1039/C2CC16076E

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