Issue 29, 2012
From the journal:

Chemical Communications

Living radical polymerization of acrylates and acrylamides mediated by a versatile cobalt porphyrin complex†

Yaguang Zhao,a   Huilong Dong,b   Youyong Li*b  and  Xuefeng Fu*a  

* Corresponding authors

a Beijing National Laboratory for Molecular Sciences, State Key Lab of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing, China
E-mail: fuxf@pku.edu.cn
Fax: +86 10 6275 1708
Tel: +86 10 6275 6035

b Institute of Functional Nano & Soft Materials (FUNSOM) and Jiangsu Key Laboratory for Carbon-Based Functional Materials & Devices, Soochow University, Suzhou, China
E-mail: yyli@suda.edu.cn
Fax: +86 512 65882846
Tel: +86 51265882037

Abstract

Living radical polymerization (LRP) of organic and water soluble acrylates and acrylamides was mediated by a versatile cobalt porphyrin complex (TMP-OH)Co. The capability of this cobalt complex to mediate LRP in both polar and non-polar media permits the direct synthesis of useful and previously difficult to prepare functional block copolymers.

Graphical abstract: Living radical polymerization of acrylates and acrylamides mediated by a versatile cobalt porphyrin complex

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Article information

DOI
https://doi.org/10.1039/C2CC00114D
Article type
Communication
Submitted
06 Jan 2012
Accepted
16 Feb 2012
First published
17 Feb 2012

Chem. Commun., 2012,48, 3506-3508

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Living radical polymerization of acrylates and acrylamides mediated by a versatile cobalt porphyrin complex

Y. Zhao, H. Dong, Y. Li and X. Fu, Chem. Commun., 2012, 48, 3506 DOI: 10.1039/C2CC00114D

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