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Issue 9, 2012
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On the spontaneous carboxylation of 1-butyl-3-methylimidazolium acetate by carbon dioxide

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Abstract

The formation of 1-butyl-3-methylimidazolium-2-carboxylate in the mixture of CO2 with 1-butyl-3-methylimidazolium acetate under mild conditions (298 K, 0.1 MPa) has been put in evidence in the liquid phase using Raman and infrared spectroscopy complemented by DFT calculations and NMR (1H, 13C, 15N) spectroscopy.

Graphical abstract: On the spontaneous carboxylation of 1-butyl-3-methylimidazolium acetate by carbon dioxide

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Publication details

The article was received on 28 Oct 2011, accepted on 18 Nov 2011 and first published on 21 Nov 2011


Article type: Communication
DOI: 10.1039/C1CC16702B
Citation: Chem. Commun., 2012,48, 1245-1247

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    On the spontaneous carboxylation of 1-butyl-3-methylimidazolium acetate by carbon dioxide

    M. Besnard, M. I. Cabaço, F. V. Chávez, N. Pinaud, P. J. Sebastião, J. A. P. Coutinho and Y. Danten, Chem. Commun., 2012, 48, 1245
    DOI: 10.1039/C1CC16702B

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