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Issue 9, 2012
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On the spontaneous carboxylation of 1-butyl-3-methylimidazolium acetate by carbon dioxide

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Abstract

The formation of 1-butyl-3-methylimidazolium-2-carboxylate in the mixture of CO2 with 1-butyl-3-methylimidazolium acetate under mild conditions (298 K, 0.1 MPa) has been put in evidence in the liquid phase using Raman and infrared spectroscopy complemented by DFT calculations and NMR (1H, 13C, 15N) spectroscopy.

Graphical abstract: On the spontaneous carboxylation of 1-butyl-3-methylimidazolium acetate by carbon dioxide

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Article information


Submitted
28 Oct 2011
Accepted
18 Nov 2011
First published
21 Nov 2011

Chem. Commun., 2012,48, 1245-1247
Article type
Communication

On the spontaneous carboxylation of 1-butyl-3-methylimidazolium acetate by carbon dioxide

M. Besnard, M. I. Cabaço, F. V. Chávez, N. Pinaud, P. J. Sebastião, J. A. P. Coutinho and Y. Danten, Chem. Commun., 2012, 48, 1245
DOI: 10.1039/C1CC16702B

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