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Issue 2, 2012
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Two-stage optimization of a supramolecular catalyst for catalytic asymmetric hydroboration

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Abstract

Systematic changes, first to the structure of the catalyst scaffold and then to the ligating groups, are used to fine tune supramolecular catalysts to achieve high regioselectivity (95–98%) and high enantioselectivity (94–97% ee) across a series of meta-substituted styrenes varying in electronic character.

Graphical abstract: Two-stage optimization of a supramolecular catalyst for catalytic asymmetric hydroboration

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Publication details

The article was received on 03 Oct 2011, accepted on 02 Nov 2011 and first published on 17 Nov 2011


Article type: Communication
DOI: 10.1039/C1CC16146F
Chem. Commun., 2012,48, 263-265

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    Two-stage optimization of a supramolecular catalyst for catalytic asymmetric hydroboration

    S. A. Moteki, K. Toyama, Z. Liu, J. Ma, A. E. Holmes and J. M. Takacs, Chem. Commun., 2012, 48, 263
    DOI: 10.1039/C1CC16146F

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