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Issue 3, 2012
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Understanding the regioselectivity in Scholl reactions for the synthesis of oligoarenes

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Abstract

A short reaction sequence leads to oligoarene derivatives utilising a regioselective Scholl reaction for the unprecedented cyclisation to the mono-functionalised oligoarene under methanol elimination. Quantum-chemical investigations reveal the reason for the remarkably high regioselectivity.

Graphical abstract: Understanding the regioselectivity in Scholl reactions for the synthesis of oligoarenes

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Article information


Submitted
26 Sep 2011
Accepted
01 Nov 2011
First published
14 Nov 2011

Chem. Commun., 2012,48, 377-379
Article type
Communication

Understanding the regioselectivity in Scholl reactions for the synthesis of oligoarenes

M. Danz, R. Tonner and G. Hilt, Chem. Commun., 2012, 48, 377
DOI: 10.1039/C1CC15980A

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