Issue 3, 2012
From the journal:

Chemical Communications

Spontaneous self-assembly of a giant spherical metal-oxide Keplerate: addition of one building block induces “immediate” formation of the complementary one from a constitutional dynamic library†

Christian Schäffer,a   Ana Maria Todea,a   Pierre Gouzerhb  and  Achim Müller*a  

* Corresponding authors

a Fakultät für Chemie, Universität Bielefeld, Postfach 100131, 33501 Bielefeld, Germany
E-mail: a.mueller@uni-bielefeld.de
Web: http://www.uni-bielefeld.de/chemie/ac1/
Fax: +49 521-106-6003
Tel: +49 521-106-6153

b Institut Parisien de Chimie Moléculaire, UMR CNRS 7201, UPMC Univ Paris 06, Case courrier 42, 4 Place Jussieu, 75252 Paris Cedex 05, France

Abstract

The addition of dinuclear {Mo2} units to a dynamic library containing molybdates results in the spontaneous self-assembly of a giant spherical metal-oxide species of the type {(Mo)Mo5}12{Mo2}30 while the required pentagonal {(Mo)Mo5} building blocks are “immediately” formed.

Graphical abstract: Spontaneous self-assembly of a giant spherical metal-oxide Keplerate: addition of one building block induces “immediate” formation of the complementary one from a constitutional dynamic library

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Article information

DOI
https://doi.org/10.1039/C1CC15907K
Article type
Communication
Submitted
22 Sep 2011
Accepted
17 Oct 2011
First published
28 Oct 2011

Chem. Commun., 2012,48, 350-352

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Spontaneous self-assembly of a giant spherical metal-oxide Keplerate: addition of one building block induces “immediate” formation of the complementary one from a constitutional dynamic library

C. Schäffer, A. M. Todea, P. Gouzerh and A. Müller, Chem. Commun., 2012, 48, 350 DOI: 10.1039/C1CC15907K

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