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Issue 4, 2012
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Synthesis of chromans viaPd-catalyzed alkene carboetherification reactions

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Abstract

A new method for the construction of 2-substituted and 2,2-disubstituted chromans viaPd-catalyzed carboetherification reactions between aryl/alkenyl halides and 2-(but-3-en-1-yl)phenols is described. These reactions effect formation of a C–O bond and a C–C bond to afford the chroman products in good yield, and also provide stereoselective access to tricyclic chroman derivatives.

Graphical abstract: Synthesis of chromans viaPd-catalyzed alkene carboetherification reactions

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Publication details

The article was received on 22 Sep 2011, accepted on 11 Nov 2011 and first published on 24 Nov 2011


Article type: Communication
DOI: 10.1039/C1CC15880E
Chem. Commun., 2012,48, 609-611

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    Synthesis of chromans viaPd-catalyzed alkene carboetherification reactions

    A. F. Ward, Y. Xu and J. P. Wolfe, Chem. Commun., 2012, 48, 609
    DOI: 10.1039/C1CC15880E

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