Jump to main content
Jump to site search

Issue 19, 2012
Previous Article Next Article

A diastereomerically enriched, dimeric organolithium compound and the stereochemical course of its transformations

Author affiliations

Abstract

A dimeric α-silylated ethyllithium compound is presented featuring stereogenic metalated carbon centres with defined configurations. It can be generated by diastereoselective deprotonation of the corresponding ethylsilane. Reaction with Me3SnCl proceeds under inversion and the transfer of the stereoinformation is possible with dr's of up to 97 : 3.

Graphical abstract: A diastereomerically enriched, dimeric organolithium compound and the stereochemical course of its transformations

Back to tab navigation

Supplementary files

Publication details

The article was received on 21 Sep 2011, accepted on 04 Nov 2011 and first published on 23 Nov 2011


Article type: Communication
DOI: 10.1039/C1CC15872D
Chem. Commun., 2012,48, 2492-2494

  •   Request permissions

    A diastereomerically enriched, dimeric organolithium compound and the stereochemical course of its transformations

    C. Unkelbach, B. C. Abele, K. Lehmen, D. Schildbach, B. Waerder, K. Wild and C. Strohmann, Chem. Commun., 2012, 48, 2492
    DOI: 10.1039/C1CC15872D

Search articles by author

Spotlight

Advertisements