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Issue 10, 2012
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Symmetry of [N–X–N]+halogen bonds in solution

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Abstract

The first investigation of halogen bond symmetry is presented. In contrast to related hydrogen bonds, the iodous halogen bond is symmetric in solution and in the crystal. The bromous analogue is symmetric in solution, but shows asymmetry in the solid state. NMR results are in agreement with DFT predictions.

Graphical abstract: Symmetry of [N–X–N]+halogen bonds in solution

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Article information


Submitted
20 Sep 2011
Accepted
10 Oct 2011
First published
19 Oct 2011

Chem. Commun., 2012,48, 1458-1460
Article type
Communication

Symmetry of [N–X–N]+halogen bonds in solution

A. C. Carlsson, J. Gräfenstein, J. L. Laurila, J. Bergquist and M. Erdélyi, Chem. Commun., 2012, 48, 1458
DOI: 10.1039/C1CC15839B

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