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Issue 1, 2012

Synthesis of 3-substituted 1,5-aldehyde estersvia an organocatalytic highly enantioselective conjugate addition of new carbonylmethyl 2-pyridinylsulfone to enals

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Abstract

A highly enantioselective organocatalytic protocol for conjugate addition of new nucleophilic carbonylmethyl 2-pyridinylsulfone to enals has been developed in good yields and with high enantioselectivities. The resulting Michael adducts are versatile building blocks for a variety of organic transformations.

Graphical abstract: Synthesis of 3-substituted 1,5-aldehyde estersvia an organocatalytic highly enantioselective conjugate addition of new carbonylmethyl 2-pyridinylsulfone to enals

Supplementary files

Article information


Submitted
15 Sep 2011
Accepted
24 Oct 2011
First published
07 Nov 2011

Chem. Commun., 2012,48, 148-150
Article type
Communication

Synthesis of 3-substituted 1,5-aldehyde estersvia an organocatalytic highly enantioselective conjugate addition of new carbonylmethyl 2-pyridinylsulfone to enals

J. Deng, F. Wang, W. Yan, J. Zhu, H. Jiang, W. Wang and J. Li, Chem. Commun., 2012, 48, 148 DOI: 10.1039/C1CC15714K

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