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Issue 10, 2012
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A molecular [Mn14] coordination cluster featuring two slowly relaxing nanomagnets

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Abstract

An extended polypyrazolyl ligand has been used to assemble Mn ions into high spin entities, in the form of one stable molecule composed of two well defined clusters. The slow relaxation of the magnetisation observed is demonstrated to arise from each “half-SMM” composing this molecular cluster pair.

Graphical abstract: A molecular [Mn14] coordination cluster featuring two slowly relaxing nanomagnets

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Publication details

The article was received on 14 Sep 2011, accepted on 19 Oct 2011 and first published on 18 Nov 2011


Article type: Communication
DOI: 10.1039/C1CC15682A
Citation: Chem. Commun., 2012,48, 1413-1415

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    A molecular [Mn14] coordination cluster featuring two slowly relaxing nanomagnets

    J. S. Costa, L. A. Barrios, G. A. Craig, S. J. Teat, F. Luis, O. Roubeau, M. Evangelisti, A. Camón and G. Aromí, Chem. Commun., 2012, 48, 1413
    DOI: 10.1039/C1CC15682A

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