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Issue 8, 2012
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Hybrid charged heterometallic Pt–Ir complexes: tailoring excited states by taking the best of both worlds

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Abstract

The C[triple bond, length as m-dash]C-linkage of Pt(PR3)2(C[triple bond, length as m-dash]CAr)2 with (C⁁N)2Ir(N⁁N)+ (C⁁N = 2-phenylpyridine; N⁁N = bipyridyl) leads to hetero-bi- and trimetallic species exhibiting photophysical properties reminiscent of both [Pt]- and [Ir]-containing moieties through the generation of a [Pt] → [Ir] charge transfer excited state.

Graphical abstract: Hybrid charged heterometallic Pt–Ir complexes: tailoring excited states by taking the best of both worlds

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Publication details

The article was received on 06 Sep 2011, accepted on 01 Oct 2011 and first published on 12 Dec 2011


Article type: Communication
DOI: 10.1039/C1CC15507E
Citation: Chem. Commun., 2012,48, 1120-1122
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    Hybrid charged heterometallic Pt–Ir complexes: tailoring excited states by taking the best of both worlds

    A. M. Soliman, D. Fortin, P. D. Harvey and E. Zysman-Colman, Chem. Commun., 2012, 48, 1120
    DOI: 10.1039/C1CC15507E

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