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Issue 10, 2012
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Mapping the nanoparticle-coating monolayer with NMR pseudocontact shifts

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Abstract

Lanthanide ions Yb3+ and Tb3+, once bound to the monolayer of organic molecules coating the surface of gold nanoparticles, induce pseudo-contact shifts on the signals of nearby nuclear spins. This not only allows the investigation of the average structure of the ligands in the monolayer but also the mapping of the position of organic molecules bound to it.

Graphical abstract: Mapping the nanoparticle-coating monolayer with NMR pseudocontact shifts

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Publication details

The article was received on 31 Jul 2011, accepted on 12 Sep 2011 and first published on 30 Sep 2011


Article type: Communication
DOI: 10.1039/C1CC14726A
Citation: Chem. Commun., 2012,48, 1523-1525

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    Mapping the nanoparticle-coating monolayer with NMR pseudocontact shifts

    G. Guarino, F. Rastrelli and F. Mancin, Chem. Commun., 2012, 48, 1523
    DOI: 10.1039/C1CC14726A

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