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Issue 10, 2012
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Shuffle off the classic β-Si elimination by Ni-NHC cooperation: implication for C–C forming reactions involving Ni-alkyl-β-silanes

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Abstract

Via a cooperation of NHC, Si substituents and a M center, β-Si elimination was attenuated, revealing a new way to attain a high Ni-β-SiR3 : Ni-σ-SiR3 ratio. The scope is illustrated by a head-to-tail vinylsilane-α-olefin hydroalkenylation.

Graphical abstract: Shuffle off the classic β-Si elimination by Ni-NHC cooperation: implication for C–C forming reactions involving Ni-alkyl-β-silanes

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Article information


Submitted
27 Jul 2011
Accepted
07 Nov 2011
First published
25 Nov 2011

Chem. Commun., 2012,48, 1481-1483
Article type
Communication

Shuffle off the classic β-Si elimination by Ni-NHC cooperation: implication for C–C forming reactions involving Ni-alkyl-β-silanes

C. Ho and L. He, Chem. Commun., 2012, 48, 1481 DOI: 10.1039/C1CC14593B

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