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Issue 10, 2012
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A four coordinate parent imidevia a titanium nitridyl

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Abstract

Treatment of d1 [(nacnac)TiCl(Ntol2)] with NaN3 results in NaCl formation and N2 ejection to yield the first four coordinate, parent imide [(nacnac)Ti[double bond, length as m-dash]NH(Ntol2)] (nacnac[double bond, length as m-dash][ArNC(CH3)]2CH, Ar = 2,6-iPr2C6H3, tol = 4-CH3C6H4).

Graphical abstract: A four coordinate parent imidevia a titanium nitridyl

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Article information


Submitted
26 Jul 2011
Accepted
01 Sep 2011
First published
05 Oct 2011

Chem. Commun., 2012,48, 1529-1531
Article type
Communication

A four coordinate parent imidevia a titanium nitridyl

B. L. Tran, M. P. Washington, D. A. Henckel, X. Gao, H. Park, M. Pink and D. J. Mindiola, Chem. Commun., 2012, 48, 1529 DOI: 10.1039/C1CC14574F

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