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Issue 3, 2012
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Catalytic hydroboration by an imido-hydrido complex of Mo(iv)

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Abstract

The imido-hydrido complex (ArN)Mo(H)(Cl)(PMe3)3 catalyses a variety of hydroboration reactions, including the first example of catalytic addition of HBCat to nitriles to form the bis(borylated) amines RCH2N(BCat)2. The latter species easily undergoes chemoselective coupling with aldehydes R′C(O)H to yield imines RCH2N[double bond, length as m-dash]C(H)R′.

Graphical abstract: Catalytic hydroboration by an imido-hydrido complex of Mo(iv)

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Supplementary files

Article information


Submitted
24 Jul 2011
Accepted
25 Oct 2011
First published
11 Nov 2011

Chem. Commun., 2012,48, 455-457
Article type
Communication

Catalytic hydroboration by an imido-hydrido complex of Mo(IV)

A. Y. Khalimon, P. Farha, L. G. Kuzmina and G. I. Nikonov, Chem. Commun., 2012, 48, 455
DOI: 10.1039/C1CC14508H

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