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Issue 10, 2012
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Synthesis and reactivity of a uranyl-imidazolyl complex

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Abstract

Treatment of [UO2(Ar2nacnac)Cl]2 with 4 equiv. of Li(C4H5N2) results in the formation of a rare uranyl organometallic complex [Li(MeIm)][UO(μ-O)(Ar2nacnac)(μ-C,N-C4H5N2)2] (2), in moderate yield. Reaction of 2 with 1 equiv. of MCl2 (M = Fe, Co) yields the bimetallic complexes [MCl(MeIm)][UO2(Ar2nacnac)(μ-N,C-C4H5N2)2] (M = Fe, 3; M = Co, 4).

Graphical abstract: Synthesis and reactivity of a uranyl-imidazolyl complex

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Supplementary files

Article information


Submitted
30 May 2011
Accepted
26 Jul 2011
First published
22 Aug 2011

Chem. Commun., 2012,48, 1484-1486
Article type
Communication

Synthesis and reactivity of a uranyl-imidazolyl complex

M. F. Schettini, G. Wu and T. W. Hayton, Chem. Commun., 2012, 48, 1484 DOI: 10.1039/C1CC13192C

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