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Vinyl-functionalised pH-responsive hollow particles have been prepared for the first time and used to construct physical and doubly crosslinked (DX) hydrogels. The pH-responsive DX hydrogels do not redisperse, have a high storage modulus with interconnected porosity and should be useful for regenerative medicine applications.

Graphical abstract: Doubly crosslinked hydrogels prepared from pH-responsive vinyl-functionalised hollow particle dispersions

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