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Issue 5, 2012
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Remarkably high-temperature spin transition exhibited by new 2D metal–organic frameworks

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Abstract

Highly stable two-dimensional metal–organic frameworks, 2[FeII(L)2] (HL = 3-(2-pyridyl)-5-(3-pyridyl)-1,2,4-triazole (1) and 3-(3-methyl-2-pyridyl)-5-(3-pyridyl)-1,2,4-triazole (2), display well defined two-step spin crossover properties at remarkably high temperatures, namely, Tc1 = 329 K, Tc2 = 501 K for 1 and Tc1 = 351 K, Tc2 = 520 K for 2, which are the highest critical temperatures reported so far.

Graphical abstract: Remarkably high-temperature spin transition exhibited by new 2D metal–organic frameworks

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Supplementary files

Publication details

The article was received on 15 Nov 2011, accepted on 29 Jan 2012 and first published on 31 Jan 2012


Article type: Edge Article
DOI: 10.1039/C2SC00924B
Chem. Sci., 2012,3, 1629-1633

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    Remarkably high-temperature spin transition exhibited by new 2D metal–organic frameworks

    X. Bao, P. Guo, W. Liu, J. Tucek, W. Zhang, J. Leng, X. Chen, I. Gural'skiy, L. Salmon, A. Bousseksou and M. Tong, Chem. Sci., 2012, 3, 1629
    DOI: 10.1039/C2SC00924B

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