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Issue 3, 2012
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Microwave-assisted syntheses of highly CO2-selective organic cage frameworks (OCFs)

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Abstract

A series of organic cage frameworks (OCFs) were successfully synthesized through microwave-assisted Sonogashira coupling of 3-D molecular cage building blocks with various diacetylene linkers. These novel framework materials exhibited unprecedented, high ideal selectivity (up to 213/1) in adsorption of CO2 over N2 under ambient conditions.

Graphical abstract: Microwave-assisted syntheses of highly CO2-selective organic cage frameworks (OCFs)

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Article information


Submitted
22 Aug 2011
Accepted
16 Nov 2011
First published
12 Dec 2011

Chem. Sci., 2012,3, 874-877
Article type
Edge Article

Microwave-assisted syntheses of highly CO2-selective organic cage frameworks (OCFs)

Y. Jin, B. A. Voss, R. McCaffrey, C. T. Baggett, R. D. Noble and W. Zhang, Chem. Sci., 2012, 3, 874
DOI: 10.1039/C1SC00589H

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