Issue 25, 2012
From the journal:

RSC Advances

Selective deoxygenation of stearic acidvia an anhydride pathway†

Stefan A.W. Hollak,a   Johannes H. Bitter,b   Jacco van Haveren,a   Krijn P. de Jongb  and  Daan S. van Es*a  

* Corresponding authors

a Food and Biobased Research, Wageningen University and Research Centre, P.O. Box 17, Wageningen, AA, The Netherlands
E-mail: daan.vanes@wur.nl
Fax: (+31) 317 475347

b Inorganic Chemistry and Catalysis, Utrecht University, Sorbonnelaan 16, Utrecht, CA, The Netherlands

Abstract

Stearic anhydride is proposed as reactive intermediate in the hydrogen free decarbonylation and ketonization of stearic acid over Pd/Al2O3 at 523 K. This information is crucial towards developing of a selective low temperature decarbonylation process of fatty acids towards olefins.

Graphical abstract: Selective deoxygenation of stearic acid via an anhydride pathway

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Article information

DOI
https://doi.org/10.1039/C2RA21651E
Article type
Communication
Submitted
01 Aug 2012
Accepted
13 Aug 2012
First published
14 Aug 2012

RSC Adv., 2012,2, 9387-9391

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Selective deoxygenation of stearic acid via an anhydride pathway

S. A.W. Hollak, J. H. Bitter, J. V. Haveren, K. P. D. Jong and D. S. V. Es, RSC Adv., 2012, 2, 9387 DOI: 10.1039/C2RA21651E

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