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Issue 22, 2012
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CuO nano particles and [bmim]BF4: an application towards the synthesis of chiral β-seleno amino derivatives via ring opening reaction of aziridines with diorganyl diselenides

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Abstract

A series of chiral β-seleno amino derivatives were synthesized via a ring opening reaction of different aziridines with diorganyl diselenides mediated by recyclable CuO nanopowder and an ionic liquid affording the corresponding products in good to excellent yields. The [bmim]BF4 ionic liquid acts as both promoter and reaction medium. Compared to the usual organic solvents the ionic liquid exhibited better performance with the advantage of its recyclability.

Graphical abstract: CuO nano particles and [bmim]BF4: an application towards the synthesis of chiral β-seleno amino derivatives via ring opening reaction of aziridines with diorganyl diselenides

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Publication details

The article was received on 18 Jul 2012, accepted on 18 Jul 2012 and first published on 13 Aug 2012


Article type: Paper
DOI: 10.1039/C2RA21488A
RSC Adv., 2012,2, 8478-8482

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    CuO nano particles and [bmim]BF4: an application towards the synthesis of chiral β-seleno amino derivatives via ring opening reaction of aziridines with diorganyl diselenides

    S. M. Salman, S. Narayanaperumal, R. S. Schwab, C. R. Bender, O. E. D. Rodrigues and L. Dornelles, RSC Adv., 2012, 2, 8478
    DOI: 10.1039/C2RA21488A

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