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Issue 14, 2012
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Copper-catalysed addition of α-alkyl azaarenes to ethyl glyoxylatevia direct C(sp3)–H activation

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Abstract

A novel protocol for the copper-catalysed direct C(sp3)–H bond functionalisation of 2-alkyl azaarenes to C[double bond, length as m-dash]O double bonds has been developed, which expands the scope of C(sp3)–H bond activation reactions and provides new access to medicinally important azaarene derivatives.

Graphical abstract: Copper-catalysed addition of α-alkyl azaarenes to ethyl glyoxylate via direct C(sp3)–H activation

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Article information


Submitted
04 Apr 2012
Accepted
09 May 2012
First published
14 May 2012

RSC Adv., 2012,2, 5968-5971
Article type
Communication

Copper-catalysed addition of α-alkyl azaarenes to ethyl glyoxylate via direct C(sp3)–H activation

J. Jin, H. Niu, G. Qu, H. Guo and J. S. Fossey, RSC Adv., 2012, 2, 5968
DOI: 10.1039/C2RA20627G

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