Issue 3, 2012

Naphtho[1,2-b:5,6-b′]dithiophene-based conjugated polymer as a new electron donor for bulk heterojunction organic solar cells

Abstract

We report for the first time the synthesis and photovoltaic application of a naphtho[1,2-b:5,6-b′]dithiophene (NDT) containing donor–acceptor conjugated copolymer. The combination of a thiophene-bridge NDT building block with a quinoxaline acceptor unit results in a new copolymer that has an optical band gap of 1.77 eV, a HOMO level of −5.24 eV, and a hole mobility of 5.0 × 10−5 cm2 V−1 s−1. Preliminary characterization of the bulk-heterojunction solar cell device exhibits a PCE of around 1.5%.

Graphical abstract: Naphtho[1,2-b:5,6-b′]dithiophene-based conjugated polymer as a new electron donor for bulk heterojunction organic solar cells

Supplementary files

Article information

Article type
Communication
Submitted
19 Sep 2011
Accepted
14 Dec 2011
First published
06 Jan 2012

Polym. Chem., 2012,3, 601-604

Naphtho[1,2-b:5,6-b′]dithiophene-based conjugated polymer as a new electron donor for bulk heterojunction organic solar cells

P. Dutta, H. Park, W. Lee, K. Kim, I. N. Kang and S. Lee, Polym. Chem., 2012, 3, 601 DOI: 10.1039/C2PY00424K

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