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Issue 42, 2012
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Chiral imidate–ferrocenylphosphanes: synthesis and application as P,N-ligands in iridium(i)-catalyzed hydrogenation of unfunctionalized and poorly functionalized olefins

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Abstract

A small library of chiral imidate–ferrocenylphosphane ligands was efficiently synthesized (8 examples) and evaluated in the iridium(I)-catalyzed hydrogenation of unfunctionalized and poorly functionalized olefins. These catalysts perform very well in a range of examples (yields and ee's up to 100%).

Graphical abstract: Chiral imidate–ferrocenylphosphanes: synthesis and application as P,N-ligands in iridium(i)-catalyzed hydrogenation of unfunctionalized and poorly functionalized olefins

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Supplementary files

Article information


Submitted
07 May 2012
Accepted
08 Aug 2012
First published
09 Aug 2012

Org. Biomol. Chem., 2012,10, 8539-8550
Article type
Paper

Chiral imidate–ferrocenylphosphanes: synthesis and application as P,N-ligands in iridium(I)-catalyzed hydrogenation of unfunctionalized and poorly functionalized olefins

K. Bert, T. Noël, W. Kimpe, J. L. Goeman and J. Van der Eycken, Org. Biomol. Chem., 2012, 10, 8539
DOI: 10.1039/C2OB25871D

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