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Issue 42, 2012
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Efficient synthesis of N-(buta-2,3-dienyl) amides from terminal N-propargyl amides and their synthetic potential towards oxazoline derivatives

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Abstract

A series of N-allenyl amides was prepared conveniently from N-propargyl amides in good to excellent yields via a modified procedure developed in this group. The palladium-catalyzed coupling–cyclization of these prepared N-allenyl amides in the presence of organic iodides has been developed affording the oxazoline derivatives efficiently.

Graphical abstract: Efficient synthesis of N-(buta-2,3-dienyl) amides from terminal N-propargyl amides and their synthetic potential towards oxazoline derivatives

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Publication details

The article was received on 06 Jul 2012, accepted on 05 Sep 2012 and first published on 06 Sep 2012


Article type: Paper
DOI: 10.1039/C2OB26291F
Org. Biomol. Chem., 2012,10, 8465-8470

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    Efficient synthesis of N-(buta-2,3-dienyl) amides from terminal N-propargyl amides and their synthetic potential towards oxazoline derivatives

    B. Chen, N. Wang, W. Fan and S. Ma, Org. Biomol. Chem., 2012, 10, 8465
    DOI: 10.1039/C2OB26291F

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