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Issue 13, 2012
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Total synthesis of (+)-anamarine

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Abstract

Total synthesis of (+)-anamarine a polyoxygenated δ-pyranone natural product was accomplished via cross-metathesis protocol starting from 3-butene-1-ol and glycidol. Other key features of this synthetic strategy include use of Sharpless asymmetric epoxidation, dihydroxylation, and deoxygenation-isomerization through allene rearrangement.

Graphical abstract: Total synthesis of (+)-anamarine

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Article information


Submitted
18 Nov 2011
Accepted
14 Jan 2012
First published
17 Jan 2012

Org. Biomol. Chem., 2012,10, 2647-2655
Article type
Paper

Total synthesis of (+)-anamarine

K. S. Kumar and C. S. Reddy, Org. Biomol. Chem., 2012, 10, 2647
DOI: 10.1039/C2OB06940G

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